Monodisperse microisland formation on Ni/Ru(0001) monolayers.

The creation of identical microislands consisting of Ni trimers and multiples thereof on Ru(0001) induced by oxygen adsorption has been observed using scanning tunnelling microscopy. The island formation is caused by an oxygen induced expulsion of Ni atoms or trimers out of the moiré-distorted (densified) Ni monolayer. The exceptional stability of the Ni trimers is attributed to oxygen attachment, forming Ni-oxygen composites, as verified by detailed density functional theory calculations. The high density, identical structure, and notable thermal stability of these islands open up new perspectives for the study of the properties of nanostructured surfaces.